In a separate bowl, whisk together the dutch style cocoa powder, sugar, instant coffee, and boiling water until smooth.
In a microwave-safe bowl, melt the unsweetened chocolate.
Gently fold in about half of the vanilla batter until well combined.
Alternate spooning the chocolate and vanilla batters into checkerboard pattern in the prepared loaf pan. After all of the batter is in the loaf pan, use a wooden skewer to swirl the two batters together into a marble pattern.
Bake for about 60-70 minutes until an inserted toothpick comes out clean. Remove from oven and allow to cool in the pan for 10 minutes. Using the parchment paper remove the cake from the loaf pan and place a wire rack to cool completely.
Slice to desired thickness and serve.